A Lean‐Zinc and Zincophilic Anode for Highly Reversible Zinc Metal Batteries

نویسندگان

چکیده

Lean-zinc anode is a promising configuration that can eliminate the trade-off of energy density and cycle lifetime zinc metal (Zn0) batteries. However, there are rare investigations lean-Zn designs it remains grand change to sustain high reversibility under lean conditions. Herein, design based on hierarchical zincophilic cobalt (Co0) nanowire-decorated carbon host, which derived from ZnCo bimetallic organic framework, reported. Within anode, trace amount Zn0 acts as reservoir make up for any irreversible loss source upon cycling, while Co0 nanowires guide uniform nucleation growth through lattice matching mechanism. Consequently, (average Coulomb efficiency 99.6% 4250 cycles), low overpotential (50.8 mV at 1 mA cm−2), compact electrodeposition realized. When coupling with Zn-containing cathode, full cell delivers (99.6% cycles average) long more than 5000 cycles.

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ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2023

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202305204